Have you been waiting for Work Folder for Windows 7? Finally its here, go get it here: http://www.microsoft.com/en-us/download/details.aspx?id=42558
You will find the settings in Control Panel > System and Security > Work Folders
Other resources
Work Folder overview: http://technet.microsoft.com/en-us/library/dn265974.aspx
How to deploy a Work Folder Test Lab: http://blogs.technet.com/b/filecab/archive/2013/07/10/work-folders-test-lab-deployment.aspx
DeployWindows 